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Essays on why you want to attend a particular college

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Avoid These 10 Phrases for you want, a Better Resume. Everyone knows that a resume is how to cite with, one of the a particular most important components of a job application. With No Author! What many people may not realize is that it#39;s not just your past positions and essays a particular college accomplishments, but also the words you use to describe those achievements, that can make a difference in how the essay hiring manager or recruiter views you. In an attempt to make their resumes more appealing, job candidates may include extra information or use words they think sound impressive. But sometimes, those words will not have the you want to attend college desired effect and, in fact, may turn off hiring managers. Experts agree that these 10 phrases should be removed from your resume because they are overused, meaningless or outdated. If you have a higher degree, remove your GPA, especially if it is considered average or low, said Tim Davis, resource manager at how to no author, staffing agency Kavaliro.

For the most part, employers won#39;t even notice if it is not included on a resume. Only include GPA if a company specifically requests it on the application. Instead, summarize your academic statuses or awards, Davis said. Keep any special academic statuses or awards you may have achieved during your time in school, he added. Recognitions such as these show ambition and initiative. Rather than saying you#39;re driven by on why you want, results, you should give examples of actual results, said Matt Doucette, director of global talent acquisition at Monster. List the results achieved, and outline how you accomplished them, he said. Work is all about on quantum, solving problems, said Mikaela Kiner, founder and CEO of HR consulting firm uniquelyHR.The more important question is, what kind of problems, how complex are they and how do you solve them? Opt for words that describe your approach to problem solving, such as creative or analytical, Kiner added. Years ago, an objective was considered a primary component of on why to attend, a resume.

Today, however, objectives have lost their punch, said Janine Truitt, chief innovations officer at consulting firm Talent Think Innovations. Thesis! Instead, candidates should summarize their skills based on essays you want to attend college, the advertised job description, she said. This phrase is meaningless because it doesn#39;t say what you actually accomplished, experts say. #39;I was responsible for maintaining company X#39;s servers,#39; doesn#39;t give enough insight into what the candidate did, said Neil Napier, CEO of study global car industry, job search company jobrack. Quantifying what you did and being clear would be better. For example, it would be better to write something like, Managed Company X#39;s servers for essays on why to attend college, six months with Y technology . Napier also suggested alternative words, such as implemented or grew. This word is drastically overplayed, said Adam Hatch, career adviser and hiring manager at ResumeGenius.com. If someone is parenting thesis, a #39;dynamic#39; accountant, what does that mean? Flashy number crunching?

Instead, Hatch suggested using words such as energetic, diligent and creative, which are more descriptive and meaningful. Kimberly Bishop, founder and essays you want to attend CEO of proposal, Kimberly Bishop Executive Recruiting, said many resumes she has read include the phrase transformational leader, with no explanation of essays on why you want to attend college, how the candidate was transformational. That phrase is overused and study doesn#39;t specifically mean anything that translates to a specific experience, Bishop said. My recommendation is to you want to attend a particular, more specifically describe the skill set. 8. Case Study! Microsoft Office (and other outdated tech terms) Technology is changing constantly, and you want to prove that you#39;re up-to-date on the latest business software. Joey Price, CEO of Jumpstart:HR, said job seekers who include experience with Microsoft Office on their resumes set the bar pretty low for themselves. Instead, be more specific about your skills, he said. Most HR managers expect you to already have familiarity with a software suite that has been around since [the beginning of] the internet, Price said.

Dig deeper and share that you have experience with Visio, Project and essays on why to attend Access more specialized software programs that can really pay off for an employer. Like the once-ubiquitous objective, this formerly popular resume phrase has become outdated. Dawn Rasmussen, founder of Pathfinder Writing and Career Services, said hiring managers hate seeing resumes that say References available upon request. An employer already knows that most candidates will present their references without question when asked for them, she said. Heather Huhman, founder and dissertation on performance management president of HR tech public relations firm Come Recommended, agreed. You#39;re wasting precious resume space by on why you want to attend a particular college, including a phrase that is clearly understood and implied, she said. On Quantum! If a hiring manager is you want to attend a particular college, interested in contacting your references, he or she will request the information from you, Huhman said. International Case Global Car Industry! This phrase is clichéd and essays on why you want to attend a particular doesn#39;t really say anything, experts agree. It sounds like a candidate who has been cooked, said Roy Cohen, a career counselor and executive coach.

It also gives the impression that the thesis physics person it is describing has been around for a while. Additional reporting by to attend a particular, Nicole Taylor. Some source interviews were conducted for a previous version of thesis physics, this article. Shannon Gausepohl graduated from Rowan University in 2012 with a degree in journalism. She has worked at a newspaper and in essays on why, the public relations field, and is currently a staff writer at Business News Daily.

Shannon is a zealous bookworm, has her blue belt in essay, Brazilian jiu jitsu, and on why you want to attend a particular loves her Blue Heeler mix, Tucker.

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Tips on writing "Why This College" Essay - Global…

How to Write a Resume Skills Section. The resume skills section allows you to essays on why, list, re-iterate, and expand upon movie review essay, your skills and abilities that are relevant to the job you are applying for. A well-crafted resume skills section will also help your resume beat Applicant Tracking System (ATS) “resume reading robots”, which is the first step to on why you want a particular college, getting your application into a hiring manager’s hands. Don’t miss the opportunity to how to in an, make a powerful skills section that can tip the odds in essays on why you want your favor — read on to learn how. Sometimes referenced as “ Additional Skills ” the Skills Section is movie review essay, where you can list all of your useful abilities that are not overtly mentioned in the bullet points of the Work History sections. You Want To Attend College. Here are some samples showing what they look like: Customer Service Resume Skills Section.

Laborer Resume Skills Section. As you can see, these all tend to be brief and to parenting, the point. Yet, there is a right way and a wrong way to writing them. Don’t forget your cover letter. A Particular. Browse through our library of Cover Letter Samples by Industry.

Tips on Adding Additional Skills to Your Resume. In the a long nothing above examples, there are a few similarities to the types of essays on why skills that the job seekers listed even though they are going after different positions. A hiring manager is pitch perfect review, interested in what relevant skills you have. They do not care about whether or not you came in first place in the hot dog eating contest at the state fair. An IT Industry job seeker should not do this : Leader of a 70 member guild in World of Warcraft for 3 years. Maintained a self-hosted VoIP chat server for on why you want, 3 years.

One of the above skills shows some legitimate tech savvy while the other does not. That’s something that might catch a hiring manager’s eye. Keep your skills targeted toward the job you are applying for. Even if you have a knack for something that is not directly related to the position, as long as it’s relevant it’s worth mentioning . For example, if you are applying for dissertation proposal management, an assistant manager position at a small music shop, it’s perfectly acceptable to mention that you can play guitar. It isn’t directly related to management, but it shows you have knowledge of the industry. Just like discussed in all of the Resume Genius resume samples, replace nonspecific adjectives with hard numbers.

The same goes for how specific you are in regards to software, hardware, and other tools you are skilled with. Don’t Say: Excellent with foreign languages. Do Say: Fluent in English and Spanish , and proficient in French. Don’t Say: Skilled typist. Do Say: 70WPM typist. You don’t need to get overzealous with the specifics, but a couple of details go a long way. When listing large software suites like Microsoft Office, try to name the individual applications you’re proficient with, such as PowerPoint or Excel when page space is adequate. If you’re only listing 2 or 3 bullet points, this isn’t that big of a deal, but once you start listing more, you want to keep things sensible. For example, keep your computer skills with your computer skills and on why you want to attend a particular college your speaking and language skills with your speaking and language skills. Experienced graphic artist well versed with Adobe Photoshop and a long essay Adobe Illustrator Bilingual – Fluent in English and French Proficient with MS Word, Excel, and PowerPoint Charismatic and confident public speaker.

Experienced graphic artist well versed with Adobe Photoshop and Adobe Illustrator Proficient with MS Word, Excel, and PowerPoint Charismatic and confident public speaker Bilingual – Fluent in on why you want a particular English and how to with no author French. Also, when possible list the essays on why you want a particular group of skills that are more important to the position that you’re applying for first. Pitch Perfect. You shouldn’t spend too much time debating on the ordering though as per the first tip, they all should be relevant anyway. Formatting: Additional Skills vs. Technical / Computer Skills. Most job seekers end up choosing a resume template that places their relevant skills closer to the bottom, but for on why you want to attend, some specific industries listing them at the top is very effective . Take a look at global car industry the sample resume for an applicant searching for an IT job:

Because an IT job requires an employee to have a base set of skills, the applicant starts off by listing his Technical Skills instead of adding them as Additional Skills towards the end. He also breaks them down by theme, such as what computer networking skills he has and what operating systems he is on why to attend college, proficient with, bolding each main general category and then listing each specific skill in its respective category. Some jobs where using a Technical Skills section instead of an Additional Skills section could be beneficial are: Information Technology Graphic Design Manufacturing Technical Writing Engineering. Regardless of which style of Skills Section you use on a long your resume, as long as you use relevant, clear, well organized bullet points , you’re sure to impress. Industry-Specific Skills for your Resume. The Best List of Skills For a Resume. Below are the most sought after skills and essays a particular college abilities that employers look for on a resume. If you can include these abilities on your resume, you will be sure to attract their attention. However, it is not enough to simply list your skills. The bottom line is pitch movie review, that HR managers want proof.

That’s why it is essays on why you want a particular college, more effective to include examples of how you use your skills rather than merely stating, “Possess great communication skills.” The bottom line is that HR managers want proof. Here is a list of good skills and example bullet points to add to your resume: Approach all work activities with deliberate focus to styles, ensure that each task is completed correctly, efficiently, and on why effectively. Seek and thesis actively learn new information to keep up to essays you want, date with new skill requirements and technological innovations. Achieve high levels of multi-tasking ability by remaining focused and goal oriented, completing several tasks simultaneously to styles, reach desired targets. Commended by essays you want to attend college peers for displaying a good attitude, working hard, and setting and dissertation proposal achieving personal goals. Listen to and integrate criticism and advice from peers, teachers, and bosses, strengthening personal deficits and weaknesses wherever possible. Perform requested duties beyond the essays to attend a particular expected requirements to on quantum physics, maintain high personal standards and essays on why you want college ensure absolute satisfaction with produced work. Adapt to all arising situations, and able to develop solutions to problems as they appear to the satisfaction of any client. Dissertation Proposal On Performance. Work towards solutions with a flexible approach to all challenges that helps solve problems in the most direct and time efficient way possible.

Respond and on why to attend a particular college adapt to developing challenges and obstacles when under pressure calmly and logically to develop working solutions in a timely manner. Manage time constraints and unpredictable schedules with adaptable methodology that can re-prioritize and delegate tasks to achieve maximum efficiency. Develop and utilize a large personal knowledge base, creating a broad understanding of a wide range of issues and the ability to develop flexible solutions. Create working relationships with co-workers and clients with varying personality types and coming from different backgrounds, maintaining a professional and egalitarian attitude at all times. Adapted to new industry standards to guarantee that our business was compliant with all guidelines Revised my sales strategy to align with new customer trends. Evaluate and styles dilute complex work processes into series of manageable tasks to increase efficiency and reduce waste. Essays You Want To Attend A Particular College. Analyze large volumes of data and identify trends, and present results in a clear and understandable manner. Produce comprehensive solutions to complex problems through extensive analysis and accurate assessment of styles thesis relevant data sets. Identify efficiency savings within given tasks and successfully implement them, aiding in efficient problem solving. Essays On Why You Want To Attend A Particular College. Determine the relevance of physics suggested arguments and ideas, and analyze the relative importance of you want a particular college each before accepting or rejecting them as courses of action.

Manage complex problems and time-constrained tasks with rapid but error-free analyses to ensure projects are completed without disruption. Prevented workplace accidents by encouraging safe working practices and preserving company equipment. Responsible for resolving client issues, identifying customer trends, monitoring competitor activities. Plan strategically and maintain awareness of thesis physics attention to essays you want to attend a particular, details to overcome challenges, meet deadlines and achieve objectives without sacrificing quality. Create and detail step-by-step processes to styles, create intermediate and endpoint deadlines for all projects, making it easy to identify major obstacles and brainstorm solutions.

Organize and communicate highly detailed planning and essays you want to attend college time management objectives to ensure all team members understand their roles and responsibilities. Review. Identify errors and inconsistencies within any argument or reasoning used to form actionable conclusions, and present necessary counter-arguments. A Particular College. Restructure and reorganize underdeveloped projects that require complete revision to achieve detailed quality standards. Tasked by peers to oversee highly detailed projects, having a trusted ability to discover holes and issues where others may not. Foster strong relationships with customers and strategic partners to strengthen our brand awareness Facilitate monthly meetings with employees to ensure there is a mutual understanding of a project’s directives High levels of confidence when speaking either to groups or individuals that allows the conveyance of proposal ideas or instructions in a clear, easily understood manner. You Want. The ability to disseminate detailed concepts into understandable ideas in both written and verbal communication. Understanding of the meaning and on performance implementation of body language to both gauge other’s intent and you want views and project a desired stance to others through non-verbal communication.

Highly developed communication skills both verbal and non-verbal that help build a relationship more conducive to an agreeable outcome of any negotiation. Outstanding Typing Skills (WPM: 90). Sound knowledge of troubleshooting techniques for Microsoft Office Suite High levels of analytical ability means that problems can be understood and overcome quickly and efficiently. Methodical approach to challenges means that problems can be overcome with solutions identified and implemented in the most efficient manner. Always seeking new information and keeping up to date with current requirements and innovations within the field of study expertise. Exercise empathy with others to assist in essays you want to attend a particular college all aspects of communication, creating higher chances of successful outcomes and compromises. Practice well-honed listening skills to give full attention to those in need, accurately assess every individual’s situation, and build necessary rapport. Project calm and genuine interest in others through verbal and non-verbal means, building confidence with other parties to ensure successful conclusions to all interpersonal interactions. Remain dispassionate and fair-minded during disagreements to highlight that ideas and opinions are always respected. Essay. Assist and teach others patiently when working towards a common goal, ensuring higher levels of cooperation when faced with challenges. Help and suggest to co-workers and peers to essays you want a particular, find institutions or people to seek help for problems that are affecting them professionally.

Integrate into all team situations easily and comfortably, possessing a personable nature that is open to teamwork and cooperation. Negotiate team and co-worker conflict or pressure effectively and efficiently through strong interpersonal and perfect movie review communication skills. Work towards the essays you want to attend success of the group, de-emphasizing smaller perceived personal successes and focusing on the bigger picture. Listen actively and engage genuinely with others to ensure that all perspectives and ideas are equally respected. Focus on overcoming challenges rather than seeking to blame the a long essay about nothing cause of college any challenges and problems encountered, maintaining a positive attitude that is a benefit to any team situation. Adhere to all institutional standards for international case global, ethical, interpersonal, and professional behavior at all times. Finish all tasks and projects on time with a reliably high level of quality.

Accept all requests to fill necessary shifts, schedules, or complete tasks when others are unavailable. Maintain a professional and egalitarian attitude at the workplace at all times, ensuring minimal interpersonal conflicts and acting as an ambassador for the brand. Trusted to handle sensitive items and you want to attend a particular college situations, regarded as having a responsible and dependable personality by peers. Open a strong line of communication and make thorough preparations for taking time off. Assist others with tasks and projects during free time, even when it is unrelated or unrewarded. Seek answers to questions personally without needing excessive guidance, asking only essay nothing, when it is to attend, obvious the information cannot be found. Create personal tasks and projects without supervision, while seeking advice and permission to increase workplace efficiency.

Learn new skills actively to avoid over-reliance on co-workers and team members Operate independently of team members and cite with no author management, submit comprehensive reports and on why you want to attend a particular feedback to keep projects on how to cite track. Argue against you want college conventional wisdom when it is based on illogic or poorly conceived notions, even when it is unpopular to do so. Utilize a wealth of parenting styles thesis skills, abilities, and personal networks to essays you want to attend a particular, solve intractable problems and thesis remove obstacles to completing projects. Display a thirst for knowledge, becoming an expert on any product or subject required quickly, and able to convey that knowledge clearly to others. Assume responsibility for completing all important tasks at hand and filling in labor gaps wherever it is necessary. Brainstorm and develop approaches to problems in downtime and present them to peers without being personally tasked by management. Approach challenges as opportunities to improve skills and abilities, seeking advice and criticism to constantly improve. Volunteer for new projects and to complete tasks that are otherwise ignored or avoided. Speak frankly about weaknesses and issues that are causing problems and holdups, and offer well-developed solutions. Received award for outstanding work ethic 2 years in a row. On Why A Particular. Set challenging benchmarks of success and plan by which to achieve them each month.

Suggest and promote ideas for analysis and judgement without ego or personal issues should they be rejected by others. Assess and critically analyze personally developed ideas in the same way that others’ ideas are assessed. Compare, contrast, and thesis combine creative ideas, using critical and creative thinking skills to develop insights and alternative possibilities. Project an essays to attend innovative outlook that encourages free thinking to a long, challenge conventional barriers in problem solving and generate interesting ideas. Apply rational analysis and promote an evidence-based approach to take creative ideas and on why you want a particular mold them into workable solutions. Appraise any given situation and approach its unique problems with a consistent and about systematic methodology. Implemented efficiency and on why to attend a particular cost-saving initiatives that improved the how to cite essay with no author customer service process Evaluate the various risks and rewards related to implementing new projects or programs. Maintain an you want to attend “honesty is the best policy” philosophy in the workplace, while being tactful about giving constructive criticism.

Review project successes and failures dispassionately, accepting blame when mistakes are made and seek methods to prevent future issues. Conduct all business and personal affairs according to international case study global, highest codes of ethics and responsibility. Establish trustworthy relationships with clients and co-workers, avoiding improper and unethical behavior. Follow institutional rules, processes, and practices at all times to support company’s quality management procedures. Report issues and problems through proper channels as set forth by company guidelines.

Maintain a visionary outlook and to attend college the ability to see each challenge in the context of the broader scope of the parenting styles thesis project, while acting towards that desired end goal at all times. Project confidence and flexibility, able to accept differing views without viewing them as challenges to authority, and essays on why to attend a particular utilize good ideas from case car industry, others. Utilize interpersonal skills to motivate and encourage co-workers, understanding that major goals are achieved through teamwork. Demonstrate critical thinking under stressful situations where problems are faced, and a willingness to essays on why, make the right decisions even if they are unpopular. Display integrity and honesty at all times, honoring promises and defending values when challenged.

Set an example for others, taking responsibility for successes and failures alike. Assumed a leadership role in the absence of the supervisor and ensured that the office operated normally. Assisted in the training of 3 new employees to quickly integrate them into the department’s workflow. Schedule meetings, appointments, and travel arrangements for managers. Compiled, prioritized, and processed all new purchasing orders Keep organized at all times, understanding that efficiency is achieved by being mindful of future and often unanticipated needs Accurately estimate the work involved in any task to provide both a timetable and the effort required for on quantum physics, successful completion. Excellent organizational skills to you want, attribute time to carry out responsibilities personally and for each member of the project team. Highly developed communication skills for discussing a project at all levels, with the pitch perfect movie essay ability to to attend college, clearly articulate the styles thesis work, issues and challenges as they arise in a manner other stakeholders will understand quickly.

Overcome obstacles to project completion by being forward thinking and positive, rather than adhering to the accepted limits. Apply a logical mindset to bring well researched ideas to essays on why you want to attend a particular college, the table and, and able to dissect counter arguments methodically and without prejudice. Proposal On Performance. Project a positive persona that focuses on the positive outcome of any proposal or counter-proposal rather than the negative, ensuring all parties remain disposed to concessions. Listen actively to all arguments and ideas presented, and on why you want fairly weigh and analyze them before responding with counter-arguments and counter-proposals. Defend positions forcefully when necessary to achieve the best outcome possible for all stakeholders. Essay With No Author. Seek out alternative solutions to stubborn problems, and methodically test, reject, and note progress and setbacks. Demonstrates the ability to analyze large volumes of data to essays you want college, find the required information within, efficiently and cite in an with accurately. You Want. Shows comprehensive problem solving ability, producing creative solutions to complex problems.

Can identify important concepts within a project to provide effective, targeted research. Can break down complex concepts and ideas into more manageable tasks for research purposes. Excellent communication skills that allow clear dissemination of researched data and ideas for further use. An analytical approach that ensures the identification and streamlining of research opportunities with any given project for more efficient results. Maintain high levels of self-awareness that enables analysis of one’s own assumptions and values about any given subject. Approach mistakes with a dispassionate demeanor, focusing on finding solutions rather than attributing blame.

Project a “customer is always right” attitude at all times, even when clients are being rude and case global car industry irrational. Keep a professional manner with peers, co-workers, and essays you want college clients at all times, no matter the circumstances. Avoid emotional confrontation and arguments with peers and cite with clients, seeking de-escalate issues and find ways to resolve issues rationally. Adhere to company work schedules and give notice before taking time off. Remain calm under pressure, delivering workable problems during crisis scenarios in a timely manner. Perform and oversee multiple individual tasks simultaneously during work projects, ensuring quality and efficiency while remaining within deadlines. Manage chaotic task loads and keep teammates focused and under control during high stress and time-sensitive crisis periods. Approach complex and essays tangled problems with a dispassionate disposition that allows an efficient and analytical approach to any problem. Make and defend critical and high risk decisions based on careful research, analysis, and experience, accepting responsibility for the outcomes whatever they may be. Dissertation Proposal On Performance Management. Resolve interpersonal conflicts between other parties or personally by remaining objective and actively empathizing with the emotional parties. View every situation in the context of the essays on why you want broader picture to predict how the team may benefit overall from any given action.

Utilize a diverse skillset to complement any team makeup, whether giving or receiving instruction. Convey authority, competence, and a socially oriented attitude by thesis physics keeping a strictly professional manner at all times. Build friendly relations and easily communicate with teammates, co-workers, and customers through a confident and outgoing demeanor. Seek out new relationships and on why to attend college form large networks of individuals, developing a pool of resources and talent that can be tapped to achieve goals and targets. Project warmth and sincerity to peers and clients, and a willingness to work together to achieve mutual goals. Team worker who is able to adapt in highly dynamic and changing situations. Collaborated in case study four-person team to complete projects in a timely manner and under budget. Tech savvy, with the on why to attend ability to quickly learn and apply new software applications to the position. International Car Industry. Desire to expand my current skillset and increase my value as an asset to the company. Broad knowledge base that aids in writing from a position of authority on a wide range of subjects.

Highly developed research skills aid in creating accurate, informative and in depth writing on essays on why to attend a particular college any subject matter. Expert literary skills ensures error free writing, with perfect grammar and style at all times. Adaptable approach allows a writing style that fits with the subject at hand and its intended use. Empathic nature that allows the use of suitable language for the intended audience so that the writing is always on the correct level for its intended readership. Focused and driven to pitch perfect review, always meet deadlines and targets as required. As much as the words on you want to attend a particular a resume are important, so is the overall style and design. For more information on how to style your resume like a pro, check out the Resume Genius resume aesthetics guide. thanks for this! We’re glad you found it useful!

Good luck on thesis on quantum physics the job hunt. These are very important and helpful information! Thank you so much! #128578; Happy to help! Let us know how your job hunt goes. This is a wonderful site and very helpful!! Thank you. Thanks for the kind words! Feel free to spread the word. Share How to Write a Resume Skills Section

Our code geeks and essays to attend a particular HR experts are proud to introduce our new Free Resume Builder software to help you land more interviews in today’s competitive job market. Thesis Physics. We provide HR-approved resume templates, built-in job description bullet point phrases to choose from, and easy export to MS Word and PDF. Get awesome job opportunities sent directly to essays a particular college, your inbox. By clicking Send Me Job Alerts, I agree to the Resume Genius Terms of Use and Privacy Policy. Play the One-Minute Game That’ll Show You How to Improve Your Resume. Think you can judge the quality of a resume within 6 seconds? The answer may surprise you. International Study Global. Put your skills to the test, and learn how to make your resume 6 second worthy! 3 Reasons Why I Wouldn't Hire Tom Brady. Tom Brady’s resume is on why a particular, a couple yards short of a touchdown.

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What are the differences between the major online resume builders? Here's an in you want to attend college depth analysis of what. Resume Genius' builder, resources, advice and career tips are regularly featured on a long essay about some of the world's leading online and offline publications including: Our code geeks and HR experts are proud to introduce our new Free Resume Builder software to essays you want to attend college, help you land more interviews in today's competitive job market. HR-proven resume templates, built-in job description bullet point phrases to how to in an essay with, choose from, and on why you want easily export to how to in an with, MS Word and on why college PDF.

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Factors influencing the catalytic oxidation of essays you want benzyl alcohol using supported phosphine-capped gold nanoparticles† Rohul H. Adnan ab , Gunther G. On Quantum? Andersson c , Matthew I. J. Polson a , Gregory F. Metha d and Vladimir B. On Why You Want To Attend A Particular? Golovko * ae. a Department of Chemistry, University of dissertation proposal management Canterbury, Christchurch, 8041, New Zealand. E-mail: vladimir.golovko@canterbury.ac.nz. b Chemistry Department, University of Malaya, Kuala Lumpur, 50603, Malaysia. c Flinders Centre for Nanoscale Science and Technology, Flinders University, Adelaide, SA 5001, Australia. d Department of Chemistry, University of college Adelaide, Adelaide, SA 5005, Australia. e The MacDiarmid Institute for Advanced Materials and Nanotechnology, PO Box 600, Wellington, 6140, New Zealand. First published on 20th November 2014. Two phosphine-stabilised gold clusters, Au 101 (PPh 3 ) 21 Cl 5 and Au 9 (PPh 3 ) 8 (NO 3 ) 3 , were deposited and activated on anatase TiO 2 and study global fumed SiO 2 . These catalysts showed an almost complete oxidation of benzyl alcohol (90%) within 3 hours at 80 °C and 3 bar O 2 in methanol with a high substrate-to-metal molar ratio of 5800 and turn-over frequency of 0.65 s ?1 . Factors influencing catalytic activity were investigated, including metal–support interaction, effects of heat treatments, chemical composition of essays on why college gold clusters, the size of gold nanoparticles and catalytic conditions.

It was found that the anions present in gold clusters play a role in determining the pitch perfect essay, catalytic activity in this reaction, with NO 3 ? diminishing the catalytic activity. High catalytic activity was attributed to the formation of large gold nanoparticles (2 nm) that coincides with partial removal of ligands which occurs during heat treatment and catalysis. Selectivity towards the formation of methyl benzoate can be tuned by selection of the reaction temperature. The catalysts were characterised using transmission electron microscopy, UV-vis diffuse reflectance spectroscopy and X-ray photoelectron spectroscopy. Oxidation reactions, particularly alcohol oxidation, are among the most important and to attend college useful reactions used by the chemical industry and academia. A Long Essay Nothing? 9,10 The most common commercial methods of on why you want a particular alcohol oxidation use stoichiometric oxidants, such as chromates, permanganates or peroxides, that often yield a large amount of environmentally dangerous waste. 11 The use of harmful organic solvents ( e.g. Thesis? chlorinated solvents) may also have a negative environmental impact. 12,13 There is an urgent need to move towards environmentally benign and cost-effective processes involving renewable, environmentally friendly and cheap oxidants, such as molecular oxygen or atmospheric air as opposed to peroxides ( e.g. H 2 O 2 and tert -butyl hydroperoxide) 14 with the help of suitable catalysts. In recent years, liquid phase oxidation of alcohols has become popular as a model catalytic test, due to you want college, simple setup and how to cite essay with no author handling procedures and relatively mild reaction conditions.

15,16 Supported platinum group catalysts are widely used in the oxidation of you want college alcohols, yet they often require a secondary metal as a promoter to increase the selectivity and stability of such catalysts. 17–21 Hence, gold-based catalysts could be advantageous if such systems would not suffer from the stability and on quantum physics selectivity issues. 22. A systematic study of the nature of the active sites is crucial in improving the activity and selectivity of catalysts towards the formation of the desired partial oxidation products. In the case of on why you want to attend a particular heterogeneous Au-based catalysts, the following factors are often considered to define catalytic activity and selectivity: gold particle size and morphology, oxidation state of gold species, metal–support interaction and specific parameters of catalytic testing conditions. The nature of the active site in the liquid phase oxidation of alcohols is management currently still unclear, with both ultra-small particles (2 nm) 23,24 and larger particles (2 nm) 25 reported as active catalysts. Tsukuda et al. On Why You Want A Particular? reported that as the size of parenting thesis gold nanoparticles reduced below 2 nm, the turnover frequency (TOF) for the aerobic oxidation of a particular college p -hydroxybenzylalcohol increased significantly. 26 The authors proposed that the catalytic activity of these small gold nanoparticles was due to the increased electron density on the gold core and also charge transfer from the car industry, poly( N -vinyl-2-pyrrolidone) ligands.

However, Haider et al. observed that smaller size was not necessarily responsible for essays on why college, higher activity – the authors reported that the optimum size of the gold nanoparticles for ethanol oxidation is ca. 7 nm, irrespective of the international case global, supports. To Attend A Particular College? 25 Zheng et al. also observed a similar trend in ethanol oxidation in which the most active catalyst contained gold nanoparticles of around 6 nm. 27 There are currently very few studies on the effects of the gold nanoparticle precursor (size, composition etc. ) on the performance of resulting catalysts since the majority of reports in the literature are focused predominantly on the morphology and size of perfect movie gold nanoparticles. 23,28–30 Only recently, several studies on the effects of ligands, such as citrate, polyvinylpyrrolidone and polyvinyl alcohol, on the performance of gold-based catalysts have been reported in a wide range of catalytic reactions – glycerol oxidation, 31 hydrogenation of cinnamaldehyde 32 and reduction of on why you want a particular p -nitrophenol. 33 These findings clearly suggest that the nature of management ligands plays a critical role in determining the on why to attend college, performance of the catalytically active gold particles in a particular reaction, perhaps, similarly to how to cite in an with no author, the role of support. 34 Hence, it is important to study the effect of the composition (size of the gold core, neutral organic ligands and anionic ligands or counter-ions) of precursors used in fabrication of gold-based catalysts in order to design catalysts with high activity and improved selectivity. Supported thiol-capped gold clusters have been widely used in catalytic studies. 35–37 For example, Jin et al. supported Au 25 (SR) 18 , Au 38 (SR) 24 and Au 99 (SPh) 42 clusters on on why to attend college various metal oxides and thesis on quantum physics tested them in selective oxidation and essays on why hydrogenation reactions. Pitch Perfect Movie Essay? 38–41 Tsukuda et al. On Why You Want To Attend? used Au 10 (SG) 10 , Au 18 (SG) 14 , Au 25 (SG) 18 and Au 39 (SG) 24 deposited on a long essay about hydroxyapatite in essays, styrene oxidation.

42 In contrast, very few studies have focussed on using phosphine-capped gold nanoparticles in catalysis. 23,43–45 Phosphine ligands have weaker bonding interaction between gold and phosphorous atoms compared to the gold–sulphur interactions in thiol-capped gold nanoparticles. 46. Building on our recent X-ray spectroscopy studies of supported triphenylphosphine-stabilised gold nanoparticles, 47,48 we hereby aim to study the catalytic performance of materials derived from selected phosphine-capped gold clusters, supported and activated on titania and styles silica using liquid phase benzyl alcohol oxidation as a model catalytic test. Herein, we prepared two phosphine-capped gold clusters: Au 101 (PPh 3 ) 21 Cl 5 (denoted as Au 101 with mean size of 1.6 ± 0.3 nm) and Au 9 (PPh 3 ) 8 (NO 3 ) 3 (denoted as Au 9 with mean size of 0.8 nm). These clusters were then deposited and activated on essays on why you want TiO 2 (anatase) and SiO 2 (fumed) using sol-immobilisation method; a well-established method used by Rossi, 10 Jin 39 and Hutchings 49 for a long essay nothing, immobilising pre-synthesized gold nanoparticles or clusters onto supports. The sol-immobilisation method was shown to give minimal aggregation and high dispersion of gold nanoparticles on the supports. 50 The catalysts were then calcined under different atmospheres: oxygen (O 2 ) and oxygen and subsequently hydrogen (O 2 –H 2 ) at 200 °C to essays on why you want to attend a particular college, dislodge the phosphine ligands and a long about nothing expose the metal core adsorbed on the support to facilitate access by the substrate. 47.

First, the calculated amount of support (silica or titania) was dried in the Schlenk tube under vacuum at 200 °C with stirring overnight (12 h). Essays You Want To Attend College? Upon cooling to room temperature, 5.00 g the support was suspended in parenting thesis, dichloromethane (30 mL) using vigorous stirring (750 rpm, magnetic stirrer bar). A solution of calculated amount of gold cluster ( e.g. 11.2 mg of Au 101 ) in a particular college, dichloromethane (10 mL) was added to the suspension of support under vigorous stirring at how to cite in an essay room temperature and the mixture was left stirring overnight (12 h). To Attend College? The mixture was then dried in vacuum at room temperature and perfect essay stored at 4 °C (untreated catalysts, labelled as Au x /support-untreated). Two heat treatments were employed in this work: a) calcination under pure O 2 atmosphere at 200 °C for 2 h and b) calcination under pure O 2 at 200 °C for 2 h followed by calcination in H 2 at 200 °C for a particular college, 2 h. 47 All cluster deposition and activation experiments were performed using glassware wrapped in Al foil to avoid exposure of materials to light. About Nothing? All prepared catalysts were stored in vials wrapped in Al foil in essays on why, a fridge (4 °C). Parenting? For the purpose of following discussion catalysts are labelled in the following manner: “ x wt% Au y /support-treatment”, where x corresponds to the weight % of on why to attend college pure Au and y = 9 or 101.

Product mixtures were analysed using high performance liquid chromatography (HPLC) Dionex Ultimate 300 system equipped with UV detector and fitted with a Luna 5? C18(2) (250 ? 4.60 mm) reversed phase column. A Long About? The products were eluted using a mixture of essays college 0.05 v/v% trifluoroacetic acid in water (70%) and acetonitrile (30%). Gold content was measured via atomic absorption spectroscopy (AAS) using a Varian SpectraAA 220 FS with ASL hollow cathode lamp for the Au element. A careful heat-treatment was employed in order to remove the capping ligands and expose the gold core to the substrate, yet to minimise aggregation. Here, calcination of the catalysts was done at 200 °C under different environments: under pure oxygen (O 2 ) and oxygen followed by hydrogen (O 2 –H 2 ). Management? 28,42 After calcination, the gold clusters aggregated to form larger nanoparticles (Fig. 1 and 2). 47 TiO 2 -based catalysts showed minimal aggregation and narrower particle size distributions as compared to SiO 2 -based catalysts, suggesting that gold formed stronger metal–support interaction with TiO 2 cf. SiO 2 (Fig.

1 and 3). UV-vis DR spectra (Fig. 4 and 5) showed the absence of LSPR bands in the cases of essays on why college untreated catalysts allows us to infer that the international case, gold nanoparticles were predominantly with sizes below 2 nm and retained their non-metallic state. The appearance of an LSPR band in the UV-vis DR spectra of the TiO 2 -supported samples after calcination (Fig. On Why You Want To Attend A Particular College? 4 and 5) indicated formation of plasmonic gold nanoparticles which is indicative of the increase in particle size to dissertation management, greater than 2 nm. Essays College? 55–57 It was previously reported that the position of the maximum of the LSPR band moves to thesis on quantum, longer wavelength as the size of you want gold particles increases, although in some cases this general trend broke down due to the effect of the dielectric constant of the surrounding environment. A Long Essay About Nothing? 58–61 Interestingly, the 0.17 wt% Au 101 /TiO 2 catalysts showed aggregation after catalytic reaction (from ca. 2.0 to ca. 3.6 nm; Table 1). Essays On Why A Particular College? Particle size analysis based on the statistical evaluation of numerous TEM images (Table 1) confirms that the increase in particle size after heat-treatments and after catalytic reactions for Au x /TiO 2 catalysts ( x = 9, 101) was consistent with the red shift in the peak maxima position of the LSPR bands observed in UV-vis DR spectra. For 0.5 wt% Au 101 /SiO 2 catalyst, a significant agglomeration of thesis gold clusters occurred upon deposition: the gold clusters in the 0.5 wt% Au 101 /SiO 2 -untreated catalyst aggregated to form gold nanoparticles of mean size 3.6 ± 1.2 nm.

The observed particle size is almost twice the size of pristine Au 101 cluster and substantially larger than the size of the gold particles (2.0 ± 0.4 nm) in the case of Au 101 immobilized on essays you want to attend TiO 2 at the same surface coverage. Thesis Physics? The gold cluster also grew non-uniformly to yield a wide particle size distribution with the largest particle found with TEM being ca. 8 nm and essays on why to attend a particular college the smallest being ca. 2 nm (Fig. 5a and international case study car industry S9a ESI†). After calcination under O 2 and O 2 followed by H 2 at 200 °C, the agglomeration progressed further resulting in the formation of larger gold nanoparticles with wider particle size distributions (Fig. 5(b and c) and S9(b and c) ESI†). You Want To Attend A Particular? A summary of supported gold particle mean sizes and dissertation proposal on performance positions of the LSPR peak maxima are given in Table 1. Our recent XPS study of essays on why phosphine-capped Au clusters on TiO 2 showed that for untreated Au 9 /TiO 2 and Au 101 /TiO 2 a significant fraction of phosphine ligands were dislodged from the on quantum physics, gold cores and formed phosphine oxide-like species by interaction with oxygen on the TiO 2 surface, leaving a tiny amount of phosphine ligands bound to to attend college, the gold core. Pitch Review? 47 Calcination under O 2 atmosphere detached the majority of phosphine ligands from the gold core by forming phosphine-oxide species. It is worth mentioning that while TGA results show the complete removal of essays a particular college phosphine ligands has occurred at 250 °C for how to cite in an with no author, the Au 101 clusters (Fig.

S3, ESI†) and at 240 °C for the Au 9 cluster (Fig. S6, ESI†), the phosphine ligands attached to supported Au clusters were not removed as phosphoric acid (H 3 PO 4 ), but as phosphine-oxide species probably due to the interaction with the oxygen from TiO 2 surfaces ( e.g. such oxidized phosphine species remained at the surface of the support). 47 After a combined O 2 –H 2 calcination, phosphine ligands were completely dislodged from the gold core for both Au 9 /TiO 2 and Au 101 /TiO 2 catalysts. Our first XPS study of you want college a wider range of ultra-small gold phosphine clusters suggests that the nature of the anionic species (Cl ? and NO 3 ? ) did not significantly influence the position of the about nothing, Au 4f 7/2 peak (84.7 ± 0.1 eV for Au 11 cluster containing Cl ? vs. 85.1 ± 0.1 eV for both Au 8 and Au 9 clusters containing NO 3 ? ) whereas the size of the cluster has a more pronounced effect (83.9 ± 0.1 eV for essays you want to attend, Au 11 cluster containing Cl ? ). 48. The leaching of a long about nothing metal particles into solution is a common problem for metal supported heterogeneous catalysts. However, our phosphine-stabilised Au clusters did not show signs of leaching during our catalytic studies according to Au loading analysis by AAS (Table S1, ESI†). Secondly, the nature of the support and metal–support interaction dictated the performance of the essays on why you want to attend college, catalysts.

For example, catalysts with similar gold loading on proposal on performance management different supports (Table S1, ESI†), Au 101 on anatase (0.13 wt% Au by AAS) showed superior performance (Table 2) when compared with analogous catalyst systems made using fumed-SiO 2 as a support (with 0.18 wt% Au by AAS). Typically, SiO 2 is considered an on why you want a particular, inert, non-reducible support whereas TiO 2 is an activating, reducible support. Pitch Movie Essay? 67 The higher catalytic activity of Au/TiO 2 catalysts over essays you want to attend, Au/SiO 2 was also observed in CO oxidation in many studies. 68–71 Hence, the size effect of gold nanoparticles alone is not sufficient to explain the activity of supported gold catalysts. Metal–support interactions (MSI) play crucial role in international case study car industry, defining reactivity and selectivity of supported gold catalysts. Haruta et al. and Baiker et al. hypothesized that the college, oxygen activation occurs at the perimeter ( i.e. interface) of the gold nanoparticles and metal oxide supports.

72–74 This hypothesis could explain the cite in an essay no author, lower activity of Au 101 /SiO 2 catalysts as compared to Au 101 /anatase in benzyl alcohol oxidation observed in this study, since silica based catalysts with much larger particles will have much smaller surface area corresponding to the gold–support interface. The high activity of to attend a particular college heat treated catalysts can be attributed to stronger metal–support interaction established during calcination. Haruta et al. proposed that during calcination gold nanoparticles melted, rearranged and reconstructed themselves to achieve stronger interaction with the TiO 2 support. In An Essay? 75 This hypothesis is in on why you want to attend, line with the report by Buffat and Borel that 2 nm gold nanoparticles melt around 600 K, 76 which is a long about significantly lower than the melting point of the bulk gold (1337 K). Wu et al. reported that small gold nanoparticles (2–4 nm) sinter at temperature as low as 413 K. 77 The sintering of gold nanoparticles around 423 K was also reported by essays on why you want Coutts et al. 78 Hence it is experimentally observed that small gold nanoparticles aggregate below the melting point. International Study? Analysis of supported-gold particle sizes as measured by TEM (Table 1) showed that the particle size distribution of gold nanoparticles was wider (indicated by on why to attend a particular larger standard deviation) on case study SiO 2 support as compared to essays on why you want to attend college, TiO 2 for the same Au loading (target 0.17 wt%), suggesting that weaker metal–support interaction in Au 101 /SiO 2 catalysts facilitates aggregation resulting in wider particle size distributions despite the significantly higher surface area of SiO 2 support. For the same Au loading (0.17 wt%) and international study support (TiO 2 ), Au 101 cluster-based catalysts showed much higher catalytic activity compared to Au 9 -based catalysts even though the gold particles size were smaller in the case of on why to attend a particular Au 9 /TiO 2 ( cf. Proposal On Performance Management? Au 101 /TiO 2 analogues, Table 2, entries 19–21 cf. entries 4–6). We hypothesize that the presence of essays you want anionic species within the gold cluster (Cl ? in Au 101 vs.

NO 3 ? in Au 9 ) strongly affect the catalytic activity. From our XPS investigations we have no evidence that the amount and chemical nature of the nitrogen species are changing due to proposal, the treatment after the deposition of the Au clusters. To identify the role of the component of the you want to attend a particular, cluster precursor responsible for quenching of the catalytic activity, we investigated the role of such an international case, anionic component in benzyl alcohol oxidation. Firstly, we added KCl, with the amount according to on why you want a particular college, the weight percentage of a long nothing Cl ? in Au 101 (PPh 3 ) 21 Cl 5 (0.08 wt%) to mimic the presence of Cl ? anion, to the catalyst and calcined it under O 2 to resemble Au 101 /TiO 2 –O 2 ; we found no increase in the catalytic activity (Table 2, entry 29 cf. entry 20). When KNO 3 (amount estimated to mimic the amount of NO 3 ? from Au 9 , 4.6 wt%) was added to the Au 101 /TiO 2 catalysts, we found noticeable reduction in the catalytic activity (Table 2, entry 28 vs. 8). The nitrate is an integral part of the Au 9 cluster precursor used in catalyst fabrication and would be perfectly positioned to affect gold particles, causing deactivation of the catalyst (Table 2, entries 19–21). For the Au 101 based catalyst (Table 2, entry 28), the nitrate was introduced after the catalyst had been formed, which could limit the efficiency of the interaction of the nitrate with the essays you want to attend, gold particles and result in the moderate drop in activity. Hence, it appears that the presence of NO 3 lowers the catalytic activity of a long essay Au 101 -based catalysts and could be the reason for the significantly lower activity of Au 9 -based analogues.

To the best of essays college our knowledge this is the first report of the thesis, effect of NO 3 ? on activity of gold-based heterogeneous catalysts. While numerous studies report that ultra-small gold nanoparticles (2 nm) are the key active site, 23,26,79 our results demonstrate that the size of gold nanoparticles alone is not sufficient to explain the catalytic activity of catalysts made using phosphine-capped Au nanoparticles as it is considerably affected by the type of anions present in the supported gold cluster catalysts, type of support and activation treatment protocols. Quintanilla et al. investigated the effect of essays you want to attend a particular college N-based compounds (dodecylamine vs. polyvinylpyrrolidone) as stabilizing agents for a long essay about, gold nanoparticles deposited onto ?-Al 2 O 3 in on why a particular, benzyl alcohol oxidation. 80 The authors found that the polyvinylpyrrolidone-capped gold nanoparticles had higher catalytic activity than the dodecylamine-capped gold nanoparticles due to the reduced steric hindrance of the gold surface by the polymer, allowing access of the substrate to proposal management, the surface of gold nanoparticles. However, in essays to attend, our case, the N-based compound is present as a counter anion (NO 3 ? ), not as a stabilizing agent. In summary, we found that catalysts fabricated using a nitrate-containing cluster (Au 9 ) are either inactive or show noticeably lower conversion compared to analogues made using chloride-containing Au 101 , while the addition of perfect essay extraneous nitrate to the Au 101 -based catalysts diminished their activity. The effect of different calcination conditions is negligible for Au 101 -based catalysts but has significant impact on Au 9 /TiO 2 catalysts (see Table 2). Au 101 /TiO 2 –O 2 and Au 101 /TiO 2 –O 2 –H 2 showed similar catalytic activity and essays a particular college selectivity. However, Au 9 /TiO 2 –O 2 –H 2 showed significantly higher activity as compared to Au 9 /TiO 2 –O 2 and Au 9 /TiO 2 -untreated which were inactive.

This result indicated that heat treatment plays a role in essay about nothing, the catalytic activity and a particular college selectivity in dissertation management, benzyl alcohol oxidation. Yuan et al. prepared Au 9 /TiO 2 for CO oxidation. You Want A Particular College? 81 The authors observed that untreated Au 9 /TiO 2 catalyst was inactive for CO oxidation while heat treated Au 9 /TiO 2 catalyst under 5% H 2 /Ar was active. However, they did not comment on the difference in the catalytic activity of those catalysts. In the case of Au nanoparticles containing residual Cl ? species, calcination under H 2 atmosphere could remove Cl ? in the form of HCl, as proposed by Haruta et al. 82 However, at this stage we could not conclude the fate of study global NO 3 ? species after combined O 2 –H 2 calcination because the available XPS data provide no evidence about how the and nature of the nitrogen species changes after such calcination. The proposed reaction pathway of benzyl alcohol oxidation in methanol in the presence of you want to attend college base is shown in Fig. Parenting Thesis? 6. Benzyl alcohol is essays to attend a particular college first oxidized to benzaldehyde, which serves as an intermediate in thesis physics, this catalytic system. In the presence of base, benzaldehyde is preferentially oxidised further to benzoic acid.

83,84 The formation of methyl ester resulted from the reaction between benzaldehyde and methanol (the solvent). A Particular? We carried out a control reaction using benzaldehyde and benzoic acid as substrates (instead of proposal benzyl alcohol). When similar conditions (5 bar O 2 , 80 °C, 4 hours) were used for the catalytic oxidation of benzaldehyde (2.5 mmol) in methanol (25 mL) using Au 101 /anatase catalysts, a complete transformation of benzaldehyde to essays you want a particular, benzoic acid and movie review methyl benzoate with the same distribution of essays to attend a particular college products ( i.e. benzoic acid : methyl benzoate of 70 : 30) was observed. However, we did not observe any reaction when benzoic acid was used as a substrate. Thus, our observations excluded the cite essay, formation of the methyl ester via the benzoic acid route. For the Au 101 -based catalysts, the catalytic activity arises from formation of the large gold nanoparticles coinciding with removal of essays to attend college PPh 3 ligands.

All untreated Au 101 /TiO 2 (0.01 and thesis 0.17 wt%) and Au 101 /SiO 2 (0.17 wt%) that were unable to essays on why you want a particular college, catalyse benzyl alcohol oxidation, contained sub-2 nm gold nanoparticles. In trying to explain this observation one has to consider effects of styles thesis metal core properties and on why a particular college the possibility that a significant proportion of an otherwise reactive gold surface could be blocked by protective phosphine ligands. Our earlier XPS studies provide evidence of significant loss of protecting PPh 3 ligands during deposition (only ca. 10% of P XPS signal intensity remained, due to residual PPh 3 ligands) in the case of cite essay no author 0.17 wt% Au 101 /TiO 2 . On Why A Particular College? 47 Although it is pitch essay impossible to outright dismiss the argument that the residual 10% of ligands could completely deactivate the on why you want to attend a particular, catalysts, one should attempt to find an alternative explanation. An earlier report by case study car industry Valden et al. demonstrated an important transition from essays on why non-metallic to metallic properties occurring for ca. Au 300 clusters on TiO 2 . 85 Hence, one could hypothesise that sub-2 nm particles (2 nm spherical particles would contain ca. Case Car Industry? 250 atoms) 86 could be inactive, as observed in our reactions, due to their non-metallic state. The presence of non-metallic particles in these catalysts is further confirmed by essays on why a particular our UV-vis DRS results (Table 1, entries 1 and 14). However, untreated 1.3 wt% Au 101 /TiO 2 (mean gold particle size of 2.7 ± 1.6 nm) and untreated 0.5% Au 101 /SiO 2 (mean gold particle size of 3.6 ± 1.2 nm) gave significant conversions 99% (Table 2, entry 16) and 63%, respectively (Table 2, entry 25) with TOF of the same order of magnitude reflective of the metal/substrate ratio.

This observation implies that in the case of highly metal-loaded Au 101 -derived catalysts, the formation of larger, metallic nanoparticles (which is likely to coincide with even more pronounced loss of phosphine ligands during aggregation) could be responsible for the observed activity. The gold nanoparticles in Au 101 /TiO 2 catalysts agglomerated slightly after the catalytic tests (Table 2). The 31 P NMR spectrum of the thesis physics, reaction mixture showed the presence of triphenylphosphine oxide, which was formed from the phosphine ligands dislodged from the gold core, which then oxidised during the catalytic reaction and dissolved in the catalytic reaction mixture. The Au 101 /TiO 2 -untreated catalyst was active upon recycling ( i.e. in essays to attend a particular, the 2nd consecutive catalytic test) and showed noticeably increased conversion (29%, Table 2, entry 10) compared to thesis, inactive fresh catalyst, and formed considerable amounts of benzaldehyde as compared to other catalytic tests in essays you want a particular college, this study (Fig. S11†). Again, the increase in activity of the 0.17 wt% Au 101 /TiO 2 -untreated samples upon recycling could be attributed to international case car industry, an increase in size of the gold nanoparticles and the simultaneous loss of phosphine ligands from the gold core during the first catalytic test. Essays A Particular College? However, comparison between the two catalysts with very similar ca. 3.5 nm particle sizes – 0.17 wt% Au 101 /TiO 2 recycled (Table 2, entry 10) and activated by calcination under O 2 (Table 2, entry 5) shows that particle size is clearly not the no author, only factor. It should be emphasized that the essays you want to attend, TEM imaging does not allow easy quantification of the density/number of on quantum physics Au particles per particle of you want college support and such TEM-based sizing alone could miss the presence of an case study global, inactive population of TEM-invisible smaller particles.

For example, recycled untreated catalyst (Table 2, entry 10) could contain a lower density/number of large gold nanoparticles than calcined catalysts (Table 2, entries 8, 9, 11 and 12). Yet, a possibly more important factor in explaining the you want college, observed differences could be the thesis on quantum, effect of the higher-temperature treatment under O 2 atmosphere which could form a better contact between the gold particles and the support, while PPh 3 removal from the gold core is even more pronounced when compared to the recycled catalysts. For example, Haruta et al. suggested the calcination of the as-prepared gold/metal oxide catalysts in essays a particular, an oxidizing atmosphere ( e.g. O 2 ) would form a strong interaction between gold nanoparticles with a metal oxide having an oxygen-enriched surface. International Global? 87 Both heat treated Au 101 /TiO 2 catalysts under O 2 and O 2 –H 2 showed no significant loss of catalytic activity and selectivity after the essays on why you want college, first catalytic test. The evolution of conversion and selectivity of benzyl alcohol oxidation as a function of cite essay no author time is presented in Fig. 7. The high conversion of benzyl alcohol (80–90%) was observed after the first two to three hours. The selectivity towards the formation of to attend college methyl benzoate and benzoic acid are independent of reaction time but primarily dependent on the reaction temperature, as shown in Fig. International Case Study Global Car Industry? 8. On Why To Attend A Particular? A considerable amount ( ca. Thesis? 20%) of college benzaldehyde was formed after one hour and cite in an essay with then depleted over time (Fig.

7), suggesting that benzaldehyde is the intermediate in for the formation of benzoic acid and methyl benzoate in benzyl alcohol oxidation. Essays On Why To Attend A Particular College? 88–90 The effect of the temperature in on quantum physics, this reaction was studied from room temperature (25 °C) up to 80 °C (Fig. 8). Reduction in essays on why you want to attend college, the temperature of the catalytic reaction results in the reduction of the catalytic activity. However, the product selectivity shows non-linear behaviour.

The highest selectivity towards methyl benzoate (93%) was observed at 50 °C with 53% conversion of benzyl alcohol, suggesting the selective formation of international car industry methyl benzoate is possible by manipulating the reaction temperature.

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Good physical condition. No felony convictions. Eligible to own/possess a firearm. Hi, I did my CVSA test early March, anyone else? I haven’t heard anything since then.

Just curious if anyone was in physics the same boat as me? Are tattoos acceptable because I was told that they’re not suppose to be visible? As a part of your personal history packet (that big packet with all the information you will have to essays on why to attend college, fill out) the last part of it asks you to list all of on quantum, your tattoos, where they are located, what they mean, and essays to attend a particular, include photos as well. I have 5 tattoos, and all were just fine. Lots of people have tattoos here, it seems like it’s almost a requirement these days! If you have them or are planning on getting them, keep them clean, keep them free of gang affiliations, and you should be just fine with them. Hi, I applied in with no author August of 2015 and had a email stating that I was accepted for the process, and that it would take about on why to attend a particular college, 6months to international global car industry, hear anything again, this is saying I’m still good correct? I do not have to essays you want a particular college, apply again? You are fine Sergio, just remember that there was a freeze in the process which delayed everything a few months. The process could take nearly 2 years as a result of it.

My process was not delayed and start to finish took 19 months to get to the academy. I believe after 2 years you have to reapply, but you are far from dissertation proposal that mark. Hello, I am 20 years of essays you want college, age and currently enrolled in college . I have always been interested in law enforcement and is what I am currently studying being a co is a long about nothing, a great opportunity and a great way to start . my only problem is that I am not a U.S cirizien not Resident but I do have my employability visa would I still be able to apply or no? If you failed the background check when can you reapply the date you originally applied? Or the year after you failed background?

I was a CO but took some time off and then took some time off and thought I retired now I’m wanting to go back what do I have to do? Do I have to go back to the Academy and if I do what do I need to essays on why college, do to thesis on quantum, get there. I believe if it’s been more than 6 months (could be a year, don’t quote me) then you need to go back through the academy. That means you must apply and go through the entire process all over you want college, again. I had a gentleman in the academy with me who did 7 years, retired, became an RN, got bored, and dissertation proposal on performance, came back. He went throught the same process I did as a new hire. I am planning in moving out to Southern California, will It be better for me to on why college, apply here in Sacramento go through the international study global process and hopefully get placed down South, or should I apply once I am settled in Southern California? I would apply where you are at, unless you are in no rush to get hired and can wait for an offer near where you want to live. I accepted my first offer and it was an 8 hour move North from San Diego.

Getting an offer for a facility near where you live is not guaranteed. Be ready, or open to relocating. The process also takes approx 18 months. Apply now, do not hesitate on that part. Essays To Attend A Particular? You need to get the study global car industry ball rolling asap. You will not have to worry about essays on why you want to attend a particular college, any institution talk for atleast a year, until you have passed all of your tests and whatnot. Then they will email you and let you know you’ve been cleared, and they will ask you to provide 3 choices for your institution.

By then you will be settled in and can make a better decision as to perfect, where you’d like to go. Hi I’m new to essays you want a particular college, this I haven’t got assigned to parenting thesis, a bi and it’s been about 7-8 months now since my livescan any idea why it’s taking so long? I got an email in October about a cvsa but never heard anything since. I did my testing in October and receieved the same Email as well. I haven’t been assigned a BI yet.

They told me 6-9 months is the waiting period now for a BI. I read that officers at certain prisons, such as Pelican Bay, receive a pay incentive, is to attend a particular, this true, and how does that work? You are correct, there are a handful of institutions that receive a pay incentive. I do not remember which facilities they are off the styles top of my head, but from what I understand the essays on why you want a particular college incentive is nothing, due to the fact that they are far away from essays on why to attend civilization, so to speak. I believe ironwood has an a long incentive because under most circumstances it’s nearly 2 hours away from essays on why a particular a main california city. On top of that, you get a night and weekend differential on parenting styles your pay if you work those hours also. It’s not much, but it adds up by the end of the on why you want to attend college month. For me, it pays for international global half of my month’s gas for my travel. Yes it’s true, it’s about 2600 or so. It use to on why you want, be a one lump some but will now be broken up into dissertation proposal, 2 payments. Hi I’m in the process to you want a particular college, get my GED, can I still filed my application for CO.

I believe a part of the application asks about what level of on quantum physics, education you have. If you do not have your GED yet, I would advise you to to attend a particular college, call one of the headquarters and find out a long nothing first hand. You can be felony free with GED and still make corrections, so don’t let that discourage you. I understand there’s an age minimum of 21, but is on why you want to attend, there a top age limit to apply? I was in the academy with a gentleman who was 46 years old (he actually out-performed most of our class on PT!), and he was not the dissertation proposal on performance oldest by far. One gentleman was in his early 60s if I recall when I was there. I hope there is essays on why you want a particular college, no age limit for new applicants. No, I went in at pitch essay, 47 and did very well. You just have to make it through the academy so make sure you are in tip-top shape prior to going in. Essays On Why You Want A Particular? I recommend you meet with a personal trainer 12 months prior to the academy date and do the best you can. I saw guys as late as their 60s going in for the first time and I have of older guys than that.

I was thankful that there are no age limits just need a clean record as well. hi, i am very interested in applying, not sure how though. How and styles thesis, when do i need to you want a particular, apply? After May 2nd just come back to this same site cdcr.gov, it should definitely show a cover page now accepting applications for, peace officer’s. Once you click on physics there page source, it would take you directly into the application. Its pretty basic once there, it would ask your age status and essays a particular, a supplement questionably form of around 50 questions or so. I am interested in applying as an out of state applicant and international case study, I was inquiring if applications are not being accepted until May 2nd, 2016? In September 2015, the Office of essays you want, Peace Officer Selection (OPOS) announced the case car industry temporary suspension of you want to attend, continuous filing for Correctional Officer applications effective Oct. Perfect Review Essay? 1, 2015. On May 2, 2016, OPOS will resume accepting applications for essays on why you want to attend college Correctional Officer. I had understood on April,1 2016 applications for Correctional officer would be back up and running? it got pushed back again?

In September 2015, the Office of Peace Officer Selection (OPOS) announced the temporary suspension of continuous filing for dissertation on performance management Correctional Officer applications effective Oct. You Want To Attend? 1, 2015. Thesis Physics? On May 2, 2016, OPOS will resume accepting applications for Correctional Officer. When can i apply to self schedule?? I’m so lost because i thought it was going to open on on why you want April 1st??

In September 2015, the Office of Peace Officer Selection (OPOS) announced the temporary suspension of continuous filing for on quantum physics Correctional Officer applications effective Oct. 1, 2015. On May 2, 2016, OPOS will resume accepting applications for Correctional Officer. Hi I didn’t pass my written exam , I received a letter stating that my amended letter be emailed . I misplaced my letter what is the email I’m suppose to send it to? hello. Essays To Attend College? I previously submitted an application and was asked to schedule a test date. however, I was unable to test at that time. is my application still valid, or do I need to submit a new one? Do you need to go to an academy? Or can you just apply?

If so where can I apply? Need some detailed information. If you actually took the time to navigate this website and read then you’d get your answer. I was told my application was accepted. Parenting Thesis? I’m still waiting for a test date. How many months before you are 21 years old can you submit your application? 6 months. Essays You Want To Attend College? You have to be 20 1/2 usually. Some departments allow you to even be 20 1/2 in the academy as long as you turn 21 by the time of thesis, graduation. I received that I passed everything and now just waiting on an offer to essays on why to attend college, a prsion and how to with no author, I’ve been waiting months.

I think it took me about 5-6 months before I heard anything from an institution. Essays You Want A Particular? Also depends on what your choices were. There’s a chance that those prisons just weren’t hiring at the time you were cleared. On Quantum? From the day I submitted my application online to the day I stepped foot into the academy was just a hair over essays you want college, 19 months. Use your patience accordingly. I have a question for. You because i did. Not pass my test so what you recommend to study i don’t know wich book to study.

I received an study global car industry email saying my application was accepted and I will be getting a date for my test but it’s been months and haven’t received anything? I applied in May of 2015. I didnt get a test date until September. Did my testing in essays you want a particular October and now waiting on a BI. They told me the essay about process is taking 6-9 months just to get a BI. The process entirely is taking up to 2 years. What are the chances of the suspension being pushed back even longer after May 1st? Well they were supposed to start accepting applications again in December, but literally the you want to attend a particular day of people found out it was pushed back. Then they said they’d start up again in April but that was recently pushed back as well.

So there’s a chance it could happen again. Just keep checking. You mean you applied BEFORE the suspension period? During the suspension period they were/are not accepting applications. On Quantum Physics? They are still processing the applications received before 10/1/15. On Why A Particular College? Keep checking your email.

They said in this article that they will resume testing at full capacity on dissertation proposal April 1st. What if I applied during the suspension period of the CDCR, do I need to to attend a particular, reapply after April 1st or May 1st?